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Besides behavioral observations, it is advisable to supplement the measurement of cortisol by other salivary stress markers of sympathetic-adrenal-medullary and hypothalamic-pituitary-adrenal pathways. This comprehensive assessment of the stress impact on the individual will enable one to characterize the level and type of stress. Soils in intensively farmed areas of the world are prone to degradation. Amendment of such soils with organic waste materials attempts to restore soil quality. Organic amendments are heterogeneous media, which are a source of soil organic matter (SOM) and maintain or restore chemical, physical, biological and ecological functionality. More specifically, an increase in SOM can influence the soil microclimate, microbial community structure, biomass turnover and mineralisation of nutrients. The search is on-going for locally sourced alternatives as many forms may be costly or geographically limiting. The present review focuses on a heterogeneous group of amendments i.e. biochar and brown coal waste (BCW). Both biochar (made from a variety of feedstocks at various temperatures) and BCW (mined extensively) are options that have worldwide applicability. These materials have very high C contents and soil stability, therefore can be used for long-term C sequestration to abate greenhouse gas emissions and as conditioners to improve soil quality. However, biochar is costly for large-scale applications and BCW may have inherently high moisture and pollutant contents. Future studies should focus on the long-term application of these amendments and determine the physicochemical properties of the soil, bioavailability of soil contaminants, diversity of soil communities and productivity of selected crops. Furthermore, the development of in situ technologies to lower production and processing costs of biochar and BCW would improve their economic feasibility for large-scale application. Water rights transaction has proved to be an effective method for constructing an efficient water distribution system (WDS) in various regions of the Yellow River Basin (YRB). In this study, an optimal WDS in the YRB is proposed by considering the comprehensive value of water resources, administrative management system, and market-based system. To accurately quantify the comprehensive value of water resources, the work analysis method of suspended load and bedload based on the emergy theory and time-averaged motion equation is introduced, and the quantification process of sediment transport value in the river course is formulated in the YRB. Based on this, an administrative and market-based game for water rights transaction is formulated. In this double-layer game model, the administrative authorities of the basin (Yellow River Conservancy Commission) and the corresponding regions (Water Resources Department) seek to maximize their own target revenue function/comprehensive value of the water resources. Then, the optimal trading quantity of water in each region and the bargain price can be solved. A case study is presented in the YRB to verify the effectiveness of this method. The results reveal that (1) the error rate of the riverbed shear stress as well as the sediment transport rate between the theoretical value and the calculated value does not exceed 8.76%, which indicates the rationality of the calculation method of sediment transport value; (2) the proposed dynamic differential game and pricing game perform well in determining the optimal trading quantity of water in each region. They also reveal the bargain price with optimal results of ¥ 4151.1456 half yearly and ¥ 8197.3466 per year in 2018, outperforming other methodologies. Bafilomycin A1 in vivo The persistence of groundwater contaminants is influenced by several interacting processes. Physical, physico-chemical, and (bio-)chemical processes all influence the transport of contaminants in the subsurface. However, for a given hydrogeological system, it is generally unclear to which degree each of these phenomena acts as a control on plume behaviour. Here, we present a comprehensive investigation of these processes and their influences on plume behaviour and persistence in layered sedimentary systems. We investigate different scenarios that represent fundamental configurations of common contaminant situations. A confined aquifer over- and underlain by aquitard layers is investigated in a source-removal scenario and a constant-source equilibrium scenario. Additionally, an aquitard overlain and underlain by high permeability units is investigated in a source-removal scenario. In these investigations, we vary layer thickness, as well as parameters governing advection, (back-)diffusion, sorption, and degradation. Extensive analysis of these results enables quantification of the influence of these parameters on maximum down-gradient concentration, plume persistence duration, and plume spatial extent. Finally, parameter space dimensionality reduction is used to establish trends and regimes in which certain processes dominate as controls. A lower limit to plume extent as a function of a novel constructed parameter is also determined. These results provide valuable quantitative information for the assessment of the fate of groundwater contaminants and are applicable to a wide range of aqueous-phase solutes. Nanoparticle capping agents are critical for controlling the growth, oxidation state, and final particle size during aqueous synthesis. However, despite the known phytotoxicity of cetyltrimethylammonium bromide (CTAB) to plants, it is used to synthesize metal oxide nanoparticles of uniform size and with mesoporous structure. Among the few studies that have investigated how CTAB influences nanoparticle toxicity, CTAB has never been identified as the primary cause of nanoparticle toxicity in environmental systems; rather nanoparticle surface charge or morphology was identified as the driver of toxicity in environmentally relevant systems. In the current study, CTAB release from CTAB surface modified Cu2O nanoparticles (SM-Cu2O NPs) inhibited duckweed (Landoltia punctata) growth, even when administered at subtoxic Cu concentrations. Organic ligands, such as humic acid (HA) and ethylenediaminetetraacetic acid (EDTA), lessened growth inhibition associated with exposure to SM-Cu2O NPs, likely through electrostatic and hydrophobic interactions with CTAB. Such results highlight the need for a more holistic approach to nanoparticle surface modification and improved communication between toxicologists and synthetic chemists to develop green alternatives for nanoparticle synthesis. Published by Elsevier B.V.Hexaconazole is a triazole fungicide, which is stable and difficult to degrade in the environment. The existence of hexaconazole could pose a certain risk to the environment and the health of living organisms. In this study, an efficient degradation strain B-3 (Sphingobacterium multivorum) of hexaconazole was isolated from sewage, activated sludge, and soil. The degradation efficiency of hexaconazole can reach 85.6% in 6 days at a temperature of 32.5 °C, pH of 6.31, initial inoculum of 0.4 g L-1 and initial concentration of hexaconazole of 50 mg L-1. During degradation, three metabolites (M1 2-(2, 4-dichlorophenyl)-1-(1H-1, 2, 4-triazol-1-yl) hexane-2, 5-diol; M2 2-(2, 4-dichlorophenyl) hexane-1, 2-diol; M3 1H-1, 2, 4-triazole) were identified. Moreover, 45.6% hexaconazole can be degraded in 60 days in natural soil containing B-3. The results of the transcriptome sequencing indicated the presence of 864 differential genes, in which aldehyde dehydrogenase, monooxygenase, RND transporters, and ABC transporters were up-regulated. The generation of 2-(2, 4-dichlorophenyl)-1-(1H-1, 2, 4-triazol-1-yl) hexane-2, 5-diol may be due to the participation of monooxygenase. Circular supplier selection is the process of selecting suppliers in a closed-loop supply chain. Sustainable circular supplier selection addresses the social and environmental concerns in circular supplier selection problems. In this paper, for the first time, we combine the fuzzy best-worst method and the interval VIKOR technique to evaluate and prioritize sustainable suppliers in circular supply chains. The evaluation criteria are classified into three categories of economic, social, and circular factors extracted based on the domain expert’s opinions. The fuzzy best-worst method is used to weigh the criteria, and the interval VIKOR technique is applied to evaluate the suppliers in the presence of uncertainty. This study contributes to the sustainable development goals (SDG’s) of providing Decent Work and Economic Growth (SDG 8) and Responsible Consumption and Production (SDG 12). The proposed method is then used to evaluate six suppliers in the wire-and-cable industry in Iran. The results obtained from the implementation of the proposed approach and its sensitivity analysis indicate the applicability and efficiency of the proposed approach. Exposure to air pollution is associated with adverse health effects; however, the available evidence of its association with telomere length (TL), an early marker of ageing, in children is still scarce with no study available for preschool children. This study aimed to investigate the association of exposure to air pollution and traffic indicators at home and kindergarten with relative leukocyte TL (LTL) in preschool children. This cross-sectional study included 200 preschool children (5-7 years old) recruited from 27 kindergartens in Sabzevar, Iran (2017). Outdoor annual average levels PM1, PM2.5, and PM10 at residential address and kindergartens were estimated applying land use regression (LUR) models. Moreover, indoor levels of PMs at kindergartens were measured for four days in each season resulting in a total of 16 days of measurements for each kindergarten. Total streets length in different buffers and distance to major road were calculated as traffic indicators at residential address and kindergartens.esidential home were associated with shorter relative LTL in preschool children. Nowadays, research on renewable raw materials and bioresources is a new concern towards the promotion of sustainable process and product development. The use of various plant biomasses such as starch, lignocellulosic and saccharide can be considered as an alternative for using cheaper and less polluting raw materials. In this regard, pine tree biomass, a lignocellulosic forest residue that has various value-added importance and it acts as a model of economic value to the agro-industrial fields. On the other hand, in order to meet and address the challenges of ever-increasing demands of bioresources, there has been significant research interest in deciphering the molecular interactions between proteins and biomass derived substances. No study reports the significance of saccharomate® derived from pine tree biomass on the structural and thermal stability of proteins. There is a sizable interest in the interactions between proteins and biomass derived substances, owing to their utilization and applications. Herein, we used various biophysical techniques such as absorption spectroscopy, fluorescence spectroscopy, circular dichroism (CD) and dynamic light scattering (DLS) to study the impact of pine tree biomass derived saccharomate® (PBDS) on bovine serum albumin (BSA). Further for better understanding of morphological changes of BSA in presence of biomass, Transmission electron microscopy (TEM) was also studied. The present study revealed that the increasing concentration of saccharomate® perturbs structural stability however; the thermal stability of BSA remained unchanged. The transition temperature of BSA remained approximately same in presence of different concentrations of PBDS. Furthermore, the size of BSA increases from 9.22 nm to 135.58 nm in presence of higher concentration of PBDS as revealed by DLS studies. To the best of our knowledge, the results represent first detailed proof of the unusual effect of PBDS on the model protein BSA.